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内容简介:
This 2006 textbook discusses the fundamentals and applications
of statistical thermodynamics for beginning graduate students in
the physical and engineering sciences. Building on the prototypical
Maxwell–Boltzmann method and maintaining a step-by-step development
of the subject, this book assumes the reader has no previous
exposure to statistics, quantum mechanics or spectroscopy. The book
begins with the essentials of statistical thermodynamics, pauses to
recover needed knowledge from quantum mechanics and spectroscopy,
and then moves on to applications involving ideal gases, the solid
state and radiation. A full introduction to kinetic theory is
provided, including its applications to transport phenomena and
chemical kinetics. A highlight of the textbook is its discussion of
modern applications, such as laser-based diagnostics. The book
concludes with a thorough presentation of the ensemble method,
featuring its use for real gases. Numerous examples and prompted
homework problems enrich the text.
书籍目录:
Preface
1. Introduction
Part I. Fundamentals of Statistical Thermodynamics:
2. Probability and statistics
Problem set I. Probability theory and statistical mathematics
3. The statistics of independent particles
4. Thermodynamics properties in the dilute limit
Problem set II. Statistical modeling for thermodynamics
Part II. Quantum Mechanics and Spectroscopy:
5. Basics of quantum mechanics
6. Quantum analysis of internal energy modes
7. The spectroscopy of diatomic molecules
Problem set III. Quantum mechanics and spectroscopy
Part III. Statistical Thermodynamics in the Dilute Limit:
8. Interlude: from particle to assembly
9. Thermodynamic properties of the ideal gas
Problem set IV. Thermodynamic properties of the ideal gas
10. Statistical thermodynamics for ideal gas mixtures
11. Concentration and temperature measurements
Problem set V. Chemical equilibrium and diagnostics
Part IV. Statistical Thermodynamics beyond the Dilute Limit:
12. Thermodynamics and information
13. Elements of the solid state
14. Equilibrium radiation
Problem set VI. The solid state and radiation
Part V. Non-Equilibrium Statistical Thermodynamics:
15. Elementary kinetic theory
16. Kinetics of molecular transport
17. Chemical kinetics
Problem set VII. Kinetic theory and molecular transport
Part VI. The Ensemble Method of Statistical Thermodynamics:
18. The canonical and grand canonical ensembles
19. Applications of ensemble theory to real gases
Problem set VIII. Ensemble theory and the non-ideal gas
20. Whence and whither
Part VII. Appendices
Index
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书籍介绍
Building on the Maxwell-Boltzmann method of step-by-step development of the subject, this book makes few presumptions concerning students' previous exposure to statistics, quantum mechanics, or spectroscopy. The book begins with the fundamentals of statistical thermodynamics, pauses to recover needed knowledge from quantum mechanics and spectroscopy, and then moves on to applications involving ideal gases, the solid state, and radiation. A full introduction to kinetic theory is provided, including its applications to transport phenomena and chemical kinetics. Modern applications, such as laser-based diagnostics, are also discussed.
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